Synthesis and Structure of Chloro Complex of Palladium(II) with {[6-Amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic Acid
- Authors: Golubyatnikova L.G.1, Khisamutdinov R.A.1, Grabovskii S.A.1, Meshcheryakova E.S.2, Khalilov L.M.2, Kabalnova N.N.1, Murinov Y.I.1
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Affiliations:
- Ufa Institute of Chemistry
- Institute of Petrochemistry and Catalysis
- Issue: Vol 89, No 9 (2019)
- Pages: 1808-1815
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223073
- DOI: https://doi.org/10.1134/S1070363219090135
- ID: 223073
Cite item
Abstract
Palladium(II) chloro complex with {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid has been synthesized via the ligand substitution method. Composition and structure of the coordination compound have been elucidated from the combined data of elemental analysis and spectroscopy. The coordination of {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid occurs via the formation of a donor-acceptor bond between the palladium(II) ion and the nitrogen atoms in position 1 of the pyrimidine rings, chloride ions entering the inner coordination sphere of the PdCl2L2 complex, to give trans-bis({[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}-hydroxyacetyl)dichloropalladium(II).
About the authors
L. G. Golubyatnikova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054
R. A. Khisamutdinov
Ufa Institute of Chemistry
Author for correspondence.
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054
S. A. Grabovskii
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054
E. S. Meshcheryakova
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
Russian Federation, Ufa
L. M. Khalilov
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
Russian Federation, Ufa
N. N. Kabalnova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054
Yu. I. Murinov
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054