Synthesis and Structure of Chloro Complex of Palladium(II) with {[6-Amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic Acid
- Autores: Golubyatnikova L.1, Khisamutdinov R.1, Grabovskii S.1, Meshcheryakova E.2, Khalilov L.2, Kabalnova N.1, Murinov Y.1
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Afiliações:
- Ufa Institute of Chemistry
- Institute of Petrochemistry and Catalysis
- Edição: Volume 89, Nº 9 (2019)
- Páginas: 1808-1815
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223073
- DOI: https://doi.org/10.1134/S1070363219090135
- ID: 223073
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Resumo
Palladium(II) chloro complex with {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid has been synthesized via the ligand substitution method. Composition and structure of the coordination compound have been elucidated from the combined data of elemental analysis and spectroscopy. The coordination of {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid occurs via the formation of a donor-acceptor bond between the palladium(II) ion and the nitrogen atoms in position 1 of the pyrimidine rings, chloride ions entering the inner coordination sphere of the PdCl2L2 complex, to give trans-bis({[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}-hydroxyacetyl)dichloropalladium(II).
Sobre autores
L. Golubyatnikova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Rússia, pr. Oktyabrya 69, Ufa, 450054
R. Khisamutdinov
Ufa Institute of Chemistry
Autor responsável pela correspondência
Email: hisam@anrb.ru
Rússia, pr. Oktyabrya 69, Ufa, 450054
S. Grabovskii
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Rússia, pr. Oktyabrya 69, Ufa, 450054
E. Meshcheryakova
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
Rússia, Ufa
L. Khalilov
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
Rússia, Ufa
N. Kabalnova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Rússia, pr. Oktyabrya 69, Ufa, 450054
Yu. Murinov
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Rússia, pr. Oktyabrya 69, Ufa, 450054