Synthesis and Structure of Chloro Complex of Palladium(II) with {[6-Amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic Acid
- 作者: Golubyatnikova L.1, Khisamutdinov R.1, Grabovskii S.1, Meshcheryakova E.2, Khalilov L.2, Kabalnova N.1, Murinov Y.1
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隶属关系:
- Ufa Institute of Chemistry
- Institute of Petrochemistry and Catalysis
- 期: 卷 89, 编号 9 (2019)
- 页面: 1808-1815
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223073
- DOI: https://doi.org/10.1134/S1070363219090135
- ID: 223073
如何引用文章
详细
Palladium(II) chloro complex with {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid has been synthesized via the ligand substitution method. Composition and structure of the coordination compound have been elucidated from the combined data of elemental analysis and spectroscopy. The coordination of {[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}acetic acid occurs via the formation of a donor-acceptor bond between the palladium(II) ion and the nitrogen atoms in position 1 of the pyrimidine rings, chloride ions entering the inner coordination sphere of the PdCl2L2 complex, to give trans-bis({[6-amino-2-(butylsulfanyl)pyrimidin-4-yl]oxy}-hydroxyacetyl)dichloropalladium(II).
作者简介
L. Golubyatnikova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
俄罗斯联邦, pr. Oktyabrya 69, Ufa, 450054
R. Khisamutdinov
Ufa Institute of Chemistry
编辑信件的主要联系方式.
Email: hisam@anrb.ru
俄罗斯联邦, pr. Oktyabrya 69, Ufa, 450054
S. Grabovskii
Ufa Institute of Chemistry
Email: hisam@anrb.ru
俄罗斯联邦, pr. Oktyabrya 69, Ufa, 450054
E. Meshcheryakova
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
俄罗斯联邦, Ufa
L. Khalilov
Institute of Petrochemistry and Catalysis
Email: hisam@anrb.ru
俄罗斯联邦, Ufa
N. Kabalnova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
俄罗斯联邦, pr. Oktyabrya 69, Ufa, 450054
Yu. Murinov
Ufa Institute of Chemistry
Email: hisam@anrb.ru
俄罗斯联邦, pr. Oktyabrya 69, Ufa, 450054