Catalytic Cycloaminomethylation of Aminobenzamides with 1,3-Bis[dimethylamino(methoxy)methyl]thiourea


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Abstract

Efficient methods of the synthesis of cyclophanes containing the thiourea moiety via the reaction of o-, m-, and p-aminobenzamides with 1,3-bis(dimethylaminomethyl)thiourea or 1,3-bis(methoxymethyl)thiourea using NiCl2·6H2O and SmCl3·6H2O as catalysts have been developed.

About the authors

R. R. Khairullina

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Author for correspondence.
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

T. V. Tyumkina

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

A. R. Geniyatova

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

M. F. Abdullin

Ufa Institute of Chemistry of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054

A. G. Ibragimov

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

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