Reactivity of α-Amino Acids in the Reaction with Esters in Aqueous–1,4-Dioxane Media
- Authors: Kochetova L.B.1, Kustova T.P.1, Kuritsyn L.V.1
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Affiliations:
- Ivanovo State University
- Issue: Vol 88, No 1 (2018)
- Pages: 80-85
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221949
- DOI: https://doi.org/10.1134/S1070363218010127
- ID: 221949
Cite item
Abstract
The kinetics of the reaction of a series of α-amino acids with 4-nitrophenyl acetate, 4-nitrophenyl benzoate, and 2,4,6-trinitrophenyl benzoate in aqueous 1,4-dioxane medium has been studied. Kinetics of the reactions involving 4-nitrophenyl acetate and 2,4,6-trinitrophenyl benzoate has complied with the Brønsted dependence and revealed linear correlation between rate constant logarithm and the energy difference of the frontier orbitals of α-amino acids anions.
Keywords
About the authors
L. B. Kochetova
Ivanovo State University
Author for correspondence.
Email: kochetova_lb@mail.ru
Russian Federation, ul. Ermaka 39, Ivanovo, 153025
T. P. Kustova
Ivanovo State University
Email: kochetova_lb@mail.ru
Russian Federation, ul. Ermaka 39, Ivanovo, 153025
L. V. Kuritsyn
Ivanovo State University
Email: kochetova_lb@mail.ru
Russian Federation, ul. Ermaka 39, Ivanovo, 153025
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