Reactivity of α-Amino Acids in the Reaction with Esters in Aqueous–1,4-Dioxane Media
- Авторлар: Kochetova L.1, Kustova T.1, Kuritsyn L.1
-
Мекемелер:
- Ivanovo State University
- Шығарылым: Том 88, № 1 (2018)
- Беттер: 80-85
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221949
- DOI: https://doi.org/10.1134/S1070363218010127
- ID: 221949
Дәйексөз келтіру
Аннотация
The kinetics of the reaction of a series of α-amino acids with 4-nitrophenyl acetate, 4-nitrophenyl benzoate, and 2,4,6-trinitrophenyl benzoate in aqueous 1,4-dioxane medium has been studied. Kinetics of the reactions involving 4-nitrophenyl acetate and 2,4,6-trinitrophenyl benzoate has complied with the Brønsted dependence and revealed linear correlation between rate constant logarithm and the energy difference of the frontier orbitals of α-amino acids anions.
Негізгі сөздер
Авторлар туралы
L. Kochetova
Ivanovo State University
Хат алмасуға жауапты Автор.
Email: kochetova_lb@mail.ru
Ресей, ul. Ermaka 39, Ivanovo, 153025
T. Kustova
Ivanovo State University
Email: kochetova_lb@mail.ru
Ресей, ul. Ermaka 39, Ivanovo, 153025
L. Kuritsyn
Ivanovo State University
Email: kochetova_lb@mail.ru
Ресей, ul. Ermaka 39, Ivanovo, 153025
![](/img/style/loading.gif)