Reactivity of α-Amino Acids in the Reaction with Esters in Aqueous–1,4-Dioxane Media
- 作者: Kochetova L.1, Kustova T.1, Kuritsyn L.1
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隶属关系:
- Ivanovo State University
- 期: 卷 88, 编号 1 (2018)
- 页面: 80-85
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221949
- DOI: https://doi.org/10.1134/S1070363218010127
- ID: 221949
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详细
The kinetics of the reaction of a series of α-amino acids with 4-nitrophenyl acetate, 4-nitrophenyl benzoate, and 2,4,6-trinitrophenyl benzoate in aqueous 1,4-dioxane medium has been studied. Kinetics of the reactions involving 4-nitrophenyl acetate and 2,4,6-trinitrophenyl benzoate has complied with the Brønsted dependence and revealed linear correlation between rate constant logarithm and the energy difference of the frontier orbitals of α-amino acids anions.
作者简介
L. Kochetova
Ivanovo State University
编辑信件的主要联系方式.
Email: kochetova_lb@mail.ru
俄罗斯联邦, ul. Ermaka 39, Ivanovo, 153025
T. Kustova
Ivanovo State University
Email: kochetova_lb@mail.ru
俄罗斯联邦, ul. Ermaka 39, Ivanovo, 153025
L. Kuritsyn
Ivanovo State University
Email: kochetova_lb@mail.ru
俄罗斯联邦, ul. Ermaka 39, Ivanovo, 153025