The interaction of low- and medium-chlorinated biphenyls with sodium methoxide with the account for thermodynamic modeling

K. A. Plotnikova; T. I. Gorbunova; M. G. Pervova; T. V. Kulikova; A. V. Maiorova; V. I. Saloutin; O. N. Chupakhin

doi:10.1134/S1070363217050073

The interaction of low- and medium-chlorinated biphenyls with sodium methoxide with the account for thermodynamic modeling

Authors: Plotnikova K.A.¹, Gorbunova T.I.¹, Pervova M.G.¹, Kulikova T.V.², Maiorova A.V.², Saloutin V.I.¹, Chupakhin O.N.¹
Affiliations:
1. Postovskii Institute of Organic Synthesis, Ural Branch
2. Institute of Metallurgy, Ural Branch
Issue: Vol 87, No 5 (2017)
Pages: 934-939
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/219674
DOI: https://doi.org/10.1134/S1070363217050073
ID: 219674

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Abstract

The interaction of low- and medium-chlorinated congeners of polychlorinated biphenyls of the Trikhlorbifenil technical mixture with sodium methoxide in dimethylsulfoxide has been studied by means of experimental and calculation methods. Thermodynamic modeling of the process has revealed exclusive formation of the methoxy derivatives in the studied process. whereas the experiment has revealed the formation of methoxy, hydroxy, and methoxy(hydroxy) derivatives of congeners of polychlorinated biphenyls.

Keywords

polychlorinated biphenyls, congener, nucleophilic substitution, thermodynamic modeling

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The interaction of low- and medium-chlorinated biphenyls with sodium methoxide with the account for thermodynamic modeling

Full Text

Abstract

Keywords

About the authors

K. A. Plotnikova

T. I. Gorbunova

M. G. Pervova

T. V. Kulikova

A. V. Maiorova

V. I. Saloutin

O. N. Chupakhin

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