The interaction of low- and medium-chlorinated biphenyls with sodium methoxide with the account for thermodynamic modeling

Resumo

The interaction of low- and medium-chlorinated congeners of polychlorinated biphenyls of the Trikhlorbifenil technical mixture with sodium methoxide in dimethylsulfoxide has been studied by means of experimental and calculation methods. Thermodynamic modeling of the process has revealed exclusive formation of the methoxy derivatives in the studied process. whereas the experiment has revealed the formation of methoxy, hydroxy, and methoxy(hydroxy) derivatives of congeners of polychlorinated biphenyls.