The interaction of low- and medium-chlorinated biphenyls with sodium methoxide with the account for thermodynamic modeling
- Авторы: Plotnikova K.1, Gorbunova T.1, Pervova M.1, Kulikova T.2, Maiorova A.2, Saloutin V.1, Chupakhin O.1
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Учреждения:
- Postovskii Institute of Organic Synthesis, Ural Branch
- Institute of Metallurgy, Ural Branch
- Выпуск: Том 87, № 5 (2017)
- Страницы: 934-939
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219674
- DOI: https://doi.org/10.1134/S1070363217050073
- ID: 219674
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Аннотация
The interaction of low- and medium-chlorinated congeners of polychlorinated biphenyls of the Trikhlorbifenil technical mixture with sodium methoxide in dimethylsulfoxide has been studied by means of experimental and calculation methods. Thermodynamic modeling of the process has revealed exclusive formation of the methoxy derivatives in the studied process. whereas the experiment has revealed the formation of methoxy, hydroxy, and methoxy(hydroxy) derivatives of congeners of polychlorinated biphenyls.
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Об авторах
K. Plotnikova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
T. Gorbunova
Postovskii Institute of Organic Synthesis, Ural Branch
Автор, ответственный за переписку.
Email: gorbunova@ios.uran.ru
Россия, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
M. Pervova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
T. Kulikova
Institute of Metallurgy, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, Yekaterinburg
A. Maiorova
Institute of Metallurgy, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, Yekaterinburg
V. Saloutin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
O. Chupakhin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Россия, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
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