Synthesis and NMR spectroscopy of 1,3,3,5,5-pentaalkoxy-1-chlorocyclotriphosphazenes

V. P. Morgalyuk; T. S. Strelkova; A. A. Pavlov; A. G. Buyanovskaya; P. N. Ostapchuk; I. A. Godovikov; V. K. Brel’

doi:10.1134/S1070363217040120

Synthesis and NMR spectroscopy of 1,3,3,5,5-pentaalkoxy-1-chlorocyclotriphosphazenes

Authors: Morgalyuk V.P.¹, Strelkova T.S.¹, Pavlov A.A.¹, Buyanovskaya A.G.¹, Ostapchuk P.N.¹, Godovikov I.A.¹, Brel’ V.K.¹
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds
Issue: Vol 87, No 4 (2017)
Pages: 739-742
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/219212
DOI: https://doi.org/10.1134/S1070363217040120
ID: 219212

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Abstract

A series of pentaalkoxychlorocyclotriphosphazenes was synthesized. The spectral characteristics of the synthesized compounds (³¹Р, ¹H, ¹³С NMR) were studied. It was shown that the complexity of the NMR spectra of pentaalkoxychlorocyclotriphosphazenes is associated with the magnetic nonequivalence of the phosphorus atoms in the triphosphazene cycle and the hydrogen and carbon atoms in the alkoxy groups on these phosphorus atoms, as well as the cis/trans isomerism of the latter groups.