Synthesis and NMR spectroscopy of 1,3,3,5,5-pentaalkoxy-1-chlorocyclotriphosphazenes
- Autores: Morgalyuk V.1, Strelkova T.1, Pavlov A.1, Buyanovskaya A.1, Ostapchuk P.1, Godovikov I.1, Brel’ V.1
-
Afiliações:
- Nesmeyanov Institute of Organoelement Compounds
- Edição: Volume 87, Nº 4 (2017)
- Páginas: 739-742
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219212
- DOI: https://doi.org/10.1134/S1070363217040120
- ID: 219212
Citar
Resumo
A series of pentaalkoxychlorocyclotriphosphazenes was synthesized. The spectral characteristics of the synthesized compounds (31Р, 1H, 13С NMR) were studied. It was shown that the complexity of the NMR spectra of pentaalkoxychlorocyclotriphosphazenes is associated with the magnetic nonequivalence of the phosphorus atoms in the triphosphazene cycle and the hydrogen and carbon atoms in the alkoxy groups on these phosphorus atoms, as well as the cis/trans isomerism of the latter groups.
Sobre autores
V. Morgalyuk
Nesmeyanov Institute of Organoelement Compounds
Autor responsável pela correspondência
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
T. Strelkova
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
A. Pavlov
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
A. Buyanovskaya
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
P. Ostapchuk
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
I. Godovikov
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
V. Brel’
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
![](/img/style/loading.gif)