Synthesis and NMR spectroscopy of 1,3,3,5,5-pentaalkoxy-1-chlorocyclotriphosphazenes
- Авторы: Morgalyuk V.1, Strelkova T.1, Pavlov A.1, Buyanovskaya A.1, Ostapchuk P.1, Godovikov I.1, Brel’ V.1
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Учреждения:
- Nesmeyanov Institute of Organoelement Compounds
- Выпуск: Том 87, № 4 (2017)
- Страницы: 739-742
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219212
- DOI: https://doi.org/10.1134/S1070363217040120
- ID: 219212
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Аннотация
A series of pentaalkoxychlorocyclotriphosphazenes was synthesized. The spectral characteristics of the synthesized compounds (31Р, 1H, 13С NMR) were studied. It was shown that the complexity of the NMR spectra of pentaalkoxychlorocyclotriphosphazenes is associated with the magnetic nonequivalence of the phosphorus atoms in the triphosphazene cycle and the hydrogen and carbon atoms in the alkoxy groups on these phosphorus atoms, as well as the cis/trans isomerism of the latter groups.
Об авторах
V. Morgalyuk
Nesmeyanov Institute of Organoelement Compounds
Автор, ответственный за переписку.
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
T. Strelkova
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
A. Pavlov
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
A. Buyanovskaya
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
P. Ostapchuk
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
I. Godovikov
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
V. Brel’
Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Россия, ul. Vavilova 28, Moscow, 119991
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