Reactions of α-carbanions of lithium acylates with N,N-diethyl-N-chloro- and N,N-diethyl-N-bromoamines


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Аннотация

The interaction of α-carbanions of lithium acylates (prepared via metalation of acetic, butyric, or isobutyric acid with lithium diisopropylamide in tetrahydrofuran under argon atmosphere) with N,N-diethyl-N-chloro- or N,N-diethyl-N-bromoamine has resulted in the formation of succinic acid or its 2,3-diethyl- and 2,2,3,3-tetramethyl-substituted derivatives in yields of 47–66% and the corresponding α-halocarboxylic acids (12–34%). Anion–radical scheme of the reaction products formation has been suggested.

Авторлар туралы

A. Zorin

Ufa State Petroleum Technological University

Хат алмасуға жауапты Автор.
Email: chemist.518@mail.ru
Ресей, ul. Kosmonavtov 1, Ufa, 450062

A. Zainashev

Ufa State Petroleum Technological University

Email: chemist.518@mail.ru
Ресей, ul. Kosmonavtov 1, Ufa, 450062

V. Zorin

Ufa State Petroleum Technological University

Email: chemist.518@mail.ru
Ресей, ul. Kosmonavtov 1, Ufa, 450062

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