Reactions of α-carbanions of lithium acylates with N,N-diethyl-N-chloro- and N,N-diethyl-N-bromoamines
- 作者: Zorin A.1, Zainashev A.1, Zorin V.1
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隶属关系:
- Ufa State Petroleum Technological University
- 期: 卷 86, 编号 11 (2016)
- 页面: 2469-2472
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216517
- DOI: https://doi.org/10.1134/S1070363216110116
- ID: 216517
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详细
The interaction of α-carbanions of lithium acylates (prepared via metalation of acetic, butyric, or isobutyric acid with lithium diisopropylamide in tetrahydrofuran under argon atmosphere) with N,N-diethyl-N-chloro- or N,N-diethyl-N-bromoamine has resulted in the formation of succinic acid or its 2,3-diethyl- and 2,2,3,3-tetramethyl-substituted derivatives in yields of 47–66% and the corresponding α-halocarboxylic acids (12–34%). Anion–radical scheme of the reaction products formation has been suggested.
作者简介
A. Zorin
Ufa State Petroleum Technological University
编辑信件的主要联系方式.
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062
A. Zainashev
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062
V. Zorin
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062