Reactions of α-carbanions of lithium acylates with N,N-diethyl-N-chloro- and N,N-diethyl-N-bromoamines
- Authors: Zorin A.V.1, Zainashev A.T.1, Zorin V.V.1
-
Affiliations:
- Ufa State Petroleum Technological University
- Issue: Vol 86, No 11 (2016)
- Pages: 2469-2472
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216517
- DOI: https://doi.org/10.1134/S1070363216110116
- ID: 216517
Cite item
Abstract
The interaction of α-carbanions of lithium acylates (prepared via metalation of acetic, butyric, or isobutyric acid with lithium diisopropylamide in tetrahydrofuran under argon atmosphere) with N,N-diethyl-N-chloro- or N,N-diethyl-N-bromoamine has resulted in the formation of succinic acid or its 2,3-diethyl- and 2,2,3,3-tetramethyl-substituted derivatives in yields of 47–66% and the corresponding α-halocarboxylic acids (12–34%). Anion–radical scheme of the reaction products formation has been suggested.
About the authors
A. V. Zorin
Ufa State Petroleum Technological University
Author for correspondence.
Email: chemist.518@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
A. T. Zainashev
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
V. V. Zorin
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062