3-(Furyl)-3-(diethoxyphosphoryl)acrylates: Synthesis and reaction with nitromethane
- 作者: Pevzner L.1
-
隶属关系:
- St. Petersburg State Institute of Technology (Technical University)
- 期: 卷 86, 编号 7 (2016)
- 页面: 1624-1629
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215668
- DOI: https://doi.org/10.1134/S107036321607015X
- ID: 215668
如何引用文章
详细
A series of 3-(furyl)-3-(diethoxyphosphoryl)acrylates was synthesized by the reaction of 2- and 3-furoyl phosphonates with ethoxycarbonylmethylenetriphenylphosphorane. It was shown that in all cases diethoxyphosphoryl and ester groups were in trans-position with respect to the double bond disregarding the structure of the furan fragment. Potassium fluoride catalyzed addition of nitromethane to the compounds synthesized was studied. It was found that this reaction proceeded regioselectively to form 2-[(furyl)(diethoxyphosphoryl) methyl]-3-nitropropanoic acids.
作者简介
L. Pevzner
St. Petersburg State Institute of Technology (Technical University)
编辑信件的主要联系方式.
Email: pevzner_lm@list.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190013
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