3-(Furyl)-3-(diethoxyphosphoryl)acrylates: Synthesis and reaction with nitromethane
- Авторлар: Pevzner L.1
-
Мекемелер:
- St. Petersburg State Institute of Technology (Technical University)
- Шығарылым: Том 86, № 7 (2016)
- Беттер: 1624-1629
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215668
- DOI: https://doi.org/10.1134/S107036321607015X
- ID: 215668
Дәйексөз келтіру
Аннотация
A series of 3-(furyl)-3-(diethoxyphosphoryl)acrylates was synthesized by the reaction of 2- and 3-furoyl phosphonates with ethoxycarbonylmethylenetriphenylphosphorane. It was shown that in all cases diethoxyphosphoryl and ester groups were in trans-position with respect to the double bond disregarding the structure of the furan fragment. Potassium fluoride catalyzed addition of nitromethane to the compounds synthesized was studied. It was found that this reaction proceeded regioselectively to form 2-[(furyl)(diethoxyphosphoryl) methyl]-3-nitropropanoic acids.
Авторлар туралы
L. Pevzner
St. Petersburg State Institute of Technology (Technical University)
Хат алмасуға жауапты Автор.
Email: pevzner_lm@list.ru
Ресей, Moskovskii pr. 26, St. Petersburg, 190013
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