Email this article 3-(Furyl)-3-(diethoxyphosphoryl)acrylates: Synthesis and reaction with nitromethane
- Authors: Pevzner L.M.1
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Affiliations:
- St. Petersburg State Institute of Technology (Technical University)
- Issue: Vol 86, No 7 (2016)
- Pages: 1624-1629
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215668
- DOI: https://doi.org/10.1134/S107036321607015X
- ID: 215668
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Abstract
A series of 3-(furyl)-3-(diethoxyphosphoryl)acrylates was synthesized by the reaction of 2- and 3-furoyl phosphonates with ethoxycarbonylmethylenetriphenylphosphorane. It was shown that in all cases diethoxyphosphoryl and ester groups were in trans-position with respect to the double bond disregarding the structure of the furan fragment. Potassium fluoride catalyzed addition of nitromethane to the compounds synthesized was studied. It was found that this reaction proceeded regioselectively to form 2-[(furyl)(diethoxyphosphoryl) methyl]-3-nitropropanoic acids.
About the authors
L. M. Pevzner
St. Petersburg State Institute of Technology (Technical University)
Author for correspondence.
Email: pevzner_lm@list.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013
