Email this article Synthesis and properties of two new Cu(I) complexes based on 5,6-substituted imidazole-2,9-dimethyl-1,10-phenanthroline and triphenylphosphine
- Authors: Li G.F.1, Zhang X.Y.2, Li R.F.1, Liu X.F.1
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Affiliations:
- College of Chemistry and Chemical Engineering
- Food & Bioengineering Department
- Issue: Vol 86, No 2 (2016)
- Pages: 387-390
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213965
- DOI: https://doi.org/10.1134/S1070363216020316
- ID: 213965
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Abstract
Two new Cu(I) complexes, Cu(NPIP)(PPh3)2 (1) and Cu(MPIP)(PPh3)2 (2), (NHPIP: 2-(4-nitrophenyl) imidazole-2,9-dimethyl-1,10-phenanthroline; MHPIP: 2-(4-methylphenyl)imidazole-2,9-dimethyl-1,10-phenanthroline) have been synthesized and characterized by element analysis, IR and 1H NMR spectra. TG experiments demonstrated that the complexes were stable up to ca 230°C indicating their high thermal stability. According to fluorescence spectra, the complexes exhibited yellow emission at 602 nm under excitation at 260 nm.
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About the authors
G. F. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
China, Luoyang, Henan
X. Y. Zhang
Food & Bioengineering Department
Email: liuxinfang6@126.com
China, Luoyang, Henan, 471003
R. F. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
China, Luoyang, Henan
X. F. Liu
College of Chemistry and Chemical Engineering
Author for correspondence.
Email: liuxinfang6@126.com
China, Luoyang, Henan
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