Synthesis and properties of two new Cu(I) complexes based on 5,6-substituted imidazole-2,9-dimethyl-1,10-phenanthroline and triphenylphosphine
- Авторлар: Li G.1, Zhang X.2, Li R.1, Liu X.1
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Мекемелер:
- College of Chemistry and Chemical Engineering
- Food & Bioengineering Department
- Шығарылым: Том 86, № 2 (2016)
- Беттер: 387-390
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213965
- DOI: https://doi.org/10.1134/S1070363216020316
- ID: 213965
Дәйексөз келтіру
Аннотация
Two new Cu(I) complexes, Cu(NPIP)(PPh3)2 (1) and Cu(MPIP)(PPh3)2 (2), (NHPIP: 2-(4-nitrophenyl) imidazole-2,9-dimethyl-1,10-phenanthroline; MHPIP: 2-(4-methylphenyl)imidazole-2,9-dimethyl-1,10-phenanthroline) have been synthesized and characterized by element analysis, IR and 1H NMR spectra. TG experiments demonstrated that the complexes were stable up to ca 230°C indicating their high thermal stability. According to fluorescence spectra, the complexes exhibited yellow emission at 602 nm under excitation at 260 nm.
Негізгі сөздер
Авторлар туралы
G. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
ҚХР, Luoyang, Henan
X. Zhang
Food & Bioengineering Department
Email: liuxinfang6@126.com
ҚХР, Luoyang, Henan, 471003
R. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
ҚХР, Luoyang, Henan
X. Liu
College of Chemistry and Chemical Engineering
Хат алмасуға жауапты Автор.
Email: liuxinfang6@126.com
ҚХР, Luoyang, Henan
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