Synthesis and properties of two new Cu(I) complexes based on 5,6-substituted imidazole-2,9-dimethyl-1,10-phenanthroline and triphenylphosphine
- 作者: Li G.1, Zhang X.2, Li R.1, Liu X.1
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隶属关系:
- College of Chemistry and Chemical Engineering
- Food & Bioengineering Department
- 期: 卷 86, 编号 2 (2016)
- 页面: 387-390
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213965
- DOI: https://doi.org/10.1134/S1070363216020316
- ID: 213965
如何引用文章
详细
Two new Cu(I) complexes, Cu(NPIP)(PPh3)2 (1) and Cu(MPIP)(PPh3)2 (2), (NHPIP: 2-(4-nitrophenyl) imidazole-2,9-dimethyl-1,10-phenanthroline; MHPIP: 2-(4-methylphenyl)imidazole-2,9-dimethyl-1,10-phenanthroline) have been synthesized and characterized by element analysis, IR and 1H NMR spectra. TG experiments demonstrated that the complexes were stable up to ca 230°C indicating their high thermal stability. According to fluorescence spectra, the complexes exhibited yellow emission at 602 nm under excitation at 260 nm.
作者简介
G. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
中国, Luoyang, Henan
X. Zhang
Food & Bioengineering Department
Email: liuxinfang6@126.com
中国, Luoyang, Henan, 471003
R. Li
College of Chemistry and Chemical Engineering
Email: liuxinfang6@126.com
中国, Luoyang, Henan
X. Liu
College of Chemistry and Chemical Engineering
编辑信件的主要联系方式.
Email: liuxinfang6@126.com
中国, Luoyang, Henan
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