Synthesis of metallacarborane ruthenium( ii ) and ruthenium( iii ) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

I. D. Grishin; K. S. Agafonova; A. Yu. Kostyukovich; D. I. D’yachihin; I. A. Godovikov; F. M. Dolgushin; D. F. Grishin; I. T. Chizhevsky

doi:10.1007/s11172-016-1484-y

Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

作者: Grishin I.¹, Agafonova K.¹, Kostyukovich A.², D’yachihin D.², Godovikov I.², Dolgushin F.², Grishin D.¹, Chizhevsky I.²
隶属关系:
1. N. I. Lobachevsky State University of Nizhny Novgorod
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
期: 卷 65, 编号 6 (2016)
页面: 1574-1579
栏目: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/238422
DOI: https://doi.org/10.1007/s11172-016-1484-y
ID: 238422

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详细

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

作者简介

I. Grishin

N. I. Lobachevsky State University of Nizhny Novgorod

编辑信件的主要联系方式.
Email: grishin_i@ichem.unn.ru
俄罗斯联邦, 23 prosp. Gagarina, Nizhny Novgorod, 603950

K. Agafonova

N. I. Lobachevsky State University of Nizhny Novgorod

Email: grishin_i@ichem.unn.ru
俄罗斯联邦, 23 prosp. Gagarina, Nizhny Novgorod, 603950