Synthesis of metallacarborane ruthenium( ii ) and ruthenium( iii ) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

I. D. Grishin; K. S. Agafonova; A. Yu. Kostyukovich; D. I. D’yachihin; I. A. Godovikov; F. M. Dolgushin; D. F. Grishin; I. T. Chizhevsky

doi:10.1007/s11172-016-1484-y

Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

Авторлар: Grishin I.¹, Agafonova K.¹, Kostyukovich A.², D’yachihin D.², Godovikov I.², Dolgushin F.², Grishin D.¹, Chizhevsky I.²
Мекемелер:
1. N. I. Lobachevsky State University of Nizhny Novgorod
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Шығарылым: Том 65, № 6 (2016)
Беттер: 1574-1579
Бөлім: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/238422
DOI: https://doi.org/10.1007/s11172-016-1484-y
ID: 238422

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Аннотация

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

Авторлар туралы

I. Grishin

N. I. Lobachevsky State University of Nizhny Novgorod

Хат алмасуға жауапты Автор.
Email: grishin_i@ichem.unn.ru
Ресей, 23 prosp. Gagarina, Nizhny Novgorod, 603950