Synthesis of metallacarborane ruthenium( ii ) and ruthenium( iii ) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

I. D. Grishin; K. S. Agafonova; A. Yu. Kostyukovich; D. I. D’yachihin; I. A. Godovikov; F. M. Dolgushin; D. F. Grishin; I. T. Chizhevsky

doi:10.1007/s11172-016-1484-y

Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

Authors: Grishin I.D.¹, Agafonova K.S.¹, Kostyukovich A.Y.², D’yachihin D.I.², Godovikov I.A.², Dolgushin F.M.², Grishin D.F.¹, Chizhevsky I.T.²
Affiliations:
1. N. I. Lobachevsky State University of Nizhny Novgorod
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 65, No 6 (2016)
Pages: 1574-1579
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/238422
DOI: https://doi.org/10.1007/s11172-016-1484-y
ID: 238422

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Abstract

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

About the authors

I. D. Grishin

N. I. Lobachevsky State University of Nizhny Novgorod

Author for correspondence.
Email: grishin_i@ichem.unn.ru
Russian Federation, 23 prosp. Gagarina, Nizhny Novgorod, 603950

K. S. Agafonova

N. I. Lobachevsky State University of Nizhny Novgorod

Email: grishin_i@ichem.unn.ru
Russian Federation, 23 prosp. Gagarina, Nizhny Novgorod, 603950