Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions
- Authors: Grishin I.D.1, Agafonova K.S.1, Kostyukovich A.Y.2, D’yachihin D.I.2, Godovikov I.A.2, Dolgushin F.M.2, Grishin D.F.1, Chizhevsky I.T.2
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Affiliations:
- N. I. Lobachevsky State University of Nizhny Novgorod
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 65, No 6 (2016)
- Pages: 1574-1579
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238422
- DOI: https://doi.org/10.1007/s11172-016-1484-y
- ID: 238422
Cite item
Abstract
The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.
About the authors
I. D. Grishin
N. I. Lobachevsky State University of Nizhny Novgorod
Author for correspondence.
Email: grishin_i@ichem.unn.ru
Russian Federation, 23 prosp. Gagarina, Nizhny Novgorod, 603950
K. S. Agafonova
N. I. Lobachevsky State University of Nizhny Novgorod
Email: grishin_i@ichem.unn.ru
Russian Federation, 23 prosp. Gagarina, Nizhny Novgorod, 603950
A. Yu. Kostyukovich
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: grishin_i@ichem.unn.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
D. I. D’yachihin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: grishin_i@ichem.unn.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
I. A. Godovikov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: grishin_i@ichem.unn.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
F. M. Dolgushin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: grishin_i@ichem.unn.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
D. F. Grishin
N. I. Lobachevsky State University of Nizhny Novgorod
Email: grishin_i@ichem.unn.ru
Russian Federation, 23 prosp. Gagarina, Nizhny Novgorod, 603950
I. T. Chizhevsky
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: grishin_i@ichem.unn.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991