Synthesis of metallacarborane ruthenium( ii ) and ruthenium( iii ) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

I. D. Grishin; K. S. Agafonova; A. Yu. Kostyukovich; D. I. D’yachihin; I. A. Godovikov; F. M. Dolgushin; D. F. Grishin; I. T. Chizhevsky

doi:10.1007/s11172-016-1484-y

Synthesis of metallacarborane ruthenium(ii) and ruthenium(iii) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

Autores: Grishin I.¹, Agafonova K.¹, Kostyukovich A.², D’yachihin D.², Godovikov I.², Dolgushin F.², Grishin D.¹, Chizhevsky I.²
Afiliações:
1. N. I. Lobachevsky State University of Nizhny Novgorod
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Edição: Volume 65, Nº 6 (2016)
Páginas: 1574-1579
Seção: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/238422
DOI: https://doi.org/10.1007/s11172-016-1484-y
ID: 238422

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Resumo

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster , was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

Sobre autores

I. Grishin

N. I. Lobachevsky State University of Nizhny Novgorod

Autor responsável pela correspondência
Email: grishin_i@ichem.unn.ru
Rússia, 23 prosp. Gagarina, Nizhny Novgorod, 603950