电邮这篇文章 A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
- 作者: Anyushin A.1,2, Korotaev E.1, Andreeva A.1, Ryzhikov M.1, Mainichev D.1, Sokolov M.1,2, Fedin V.1,2
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隶属关系:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- 期: 卷 65, 编号 1 (2016)
- 页面: 173-180
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236874
- DOI: https://doi.org/10.1007/s11172-016-1280-8
- ID: 236874
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详细
A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.
作者简介
A. Anyushin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
编辑信件的主要联系方式.
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
E. Korotaev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
A. Andreeva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Ryzhikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. Mainichev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Sokolov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
