Мақаланы E-mail арқылы жіберу A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
- Авторлар: Anyushin A.V.1,2, Korotaev E.V.1, Andreeva A.Y.1, Ryzhikov M.R.1, Mainichev D.A.1, Sokolov M.N.1,2, Fedin V.P.1,2
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Мекемелер:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Шығарылым: Том 65, № 1 (2016)
- Беттер: 173-180
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236874
- DOI: https://doi.org/10.1007/s11172-016-1280-8
- ID: 236874
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Аннотация
A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.
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Авторлар туралы
A. Anyushin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Хат алмасуға жауапты Автор.
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
E. Korotaev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
A. Andreeva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Ryzhikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. Mainichev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Sokolov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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