Отправить статью по E-mail A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
- Авторы: Anyushin A.1,2, Korotaev E.1, Andreeva A.1, Ryzhikov M.1, Mainichev D.1, Sokolov M.1,2, Fedin V.1,2
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Учреждения:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Выпуск: Том 65, № 1 (2016)
- Страницы: 173-180
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236874
- DOI: https://doi.org/10.1007/s11172-016-1280-8
- ID: 236874
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Аннотация
A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.
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Об авторах
A. Anyushin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Автор, ответственный за переписку.
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
E. Korotaev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
A. Andreeva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Ryzhikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. Mainichev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Sokolov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
