Enviar artigo por via de e-mail A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
- Autores: Anyushin A.1,2, Korotaev E.1, Andreeva A.1, Ryzhikov M.1, Mainichev D.1, Sokolov M.1,2, Fedin V.1,2
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Afiliações:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Edição: Volume 65, Nº 1 (2016)
- Páginas: 173-180
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236874
- DOI: https://doi.org/10.1007/s11172-016-1280-8
- ID: 236874
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Resumo
A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.
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A. Anyushin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Autor responsável pela correspondência
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
E. Korotaev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
A. Andreeva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Ryzhikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. Mainichev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. Sokolov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Rússia, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
