Email this article A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
- Authors: Anyushin A.V.1,2, Korotaev E.V.1, Andreeva A.Y.1, Ryzhikov M.R.1, Mainichev D.A.1, Sokolov M.N.1,2, Fedin V.P.1,2
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Affiliations:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 65, No 1 (2016)
- Pages: 173-180
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236874
- DOI: https://doi.org/10.1007/s11172-016-1280-8
- ID: 236874
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Abstract
A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.
About the authors
A. V. Anyushin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
E. V. Korotaev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
A. Yu. Andreeva
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. R. Ryzhikov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. A. Mainichev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
M. N. Sokolov
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: anjushin@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
