Cationic polymerization of butadiene using a titanium tetrachloride— tert -butyl chloride catalytic system

V. A. Rozentsvet; V. G. Kozlov; N. A. Sablina; O. A. Stotskaya

doi:10.1007/s11172-018-2234-0

Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system

Авторлар: Rozentsvet V.A.¹, Kozlov V.G.¹, Sablina N.A.¹, Stotskaya O.A.¹
Мекемелер:
1. Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Шығарылым: Том 67, № 8 (2018)
Беттер: 1419-1425
Бөлім: Article
URL: https://journals.rcsi.science/1066-5285/article/view/242809
DOI: https://doi.org/10.1007/s11172-018-2234-0
ID: 242809

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Аннотация

Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.