Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
- Авторлар: Rozentsvet V.1, Kozlov V.1, Sablina N.1, Stotskaya O.1
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Мекемелер:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- Шығарылым: Том 67, № 8 (2018)
- Беттер: 1419-1425
- Бөлім: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/242809
- DOI: https://doi.org/10.1007/s11172-018-2234-0
- ID: 242809
Дәйексөз келтіру
Аннотация
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.
Авторлар туралы
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: rozentsvet@mail.ru
Ресей, 10 ul. Komzina, Tol’yatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Ресей, 10 ul. Komzina, Tol’yatti, 445003
N. Sablina
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Ресей, 10 ul. Komzina, Tol’yatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Ресей, 10 ul. Komzina, Tol’yatti, 445003