Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
- 作者: Rozentsvet V.1, Kozlov V.1, Sablina N.1, Stotskaya O.1
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隶属关系:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- 期: 卷 67, 编号 8 (2018)
- 页面: 1419-1425
- 栏目: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/242809
- DOI: https://doi.org/10.1007/s11172-018-2234-0
- ID: 242809
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详细
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.
作者简介
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Tol’yatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Tol’yatti, 445003
N. Sablina
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Tol’yatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Tol’yatti, 445003