Enviar artigo por via de e-mail Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
- Autores: Rozentsvet V.A.1, Kozlov V.G.1, Sablina N.A.1, Stotskaya O.A.1
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Afiliações:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- Edição: Volume 67, Nº 8 (2018)
- Páginas: 1419-1425
- Seção: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/242809
- DOI: https://doi.org/10.1007/s11172-018-2234-0
- ID: 242809
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Resumo
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.
Sobre autores
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Autor responsável pela correspondência
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Tol’yatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Tol’yatti, 445003
N. Sablina
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Tol’yatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Rússia, 10 ul. Komzina, Tol’yatti, 445003
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