Formation of Films of Tungsten and its Oxides in a High-Frequency Capacitive Discharge in a D2-O2 Mixture


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Resumo

A technique for tungsten-film deposition on different substrates in asymmetrical high-frequency (1.76 MHz) capacitive discharge in a D2−6.5 mol % O2 mixture under a total pressure of 15 Pa and at 60–130°C is considered. A circular W strip near the upper inner edge of a cylindrical hollow cathode with a radius of 4.2 cm and a height of 10 cm is the source of W particles. The smooth transition from sputtering of the inner surface to deposition occurs at a distance of about 4 cm from the upper boundary of the open part of the cathode. W, Mo, ZrO2, Si, and Cu substrates are placed in the lower closed end (bottom) and on the inner lateral cathode surface. At the upper cathode edge the sputtering yield is (4–5) × 10−2 at/ion. The mass rate of W deposition on the cathode bottom does not depend on the substrate type and is 40 μg/(cm2 h). The peculiarities of the composition, morphology, and structure of W films obtained on the lateral surface and bottom of the hollow cathode are discussed.

Sobre autores

A. Gorodetsky

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

R. Zalavutdinov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

V. Bukhovets

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

A. Markin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

A. Zakharov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

V. Zolotarevsky

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

V. Voytitsky

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

T. Rybkina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

L. Kazansky

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

I. Arkhipushkin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: aegorodetsky@mail.ru
Rússia, Moscow, 119071

E. Mukhin

Ioffe Physical-Technical Institute

Email: aegorodetsky@mail.ru
Rússia, St. Petersburg, 194021

A. Razdobarin

Ioffe Physical-Technical Institute

Email: aegorodetsky@mail.ru
Rússia, St. Petersburg, 194021

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