Vol 31, No 5 (2023)

The geochemical peculiarities of sample collection of MORB chilled glasses obtained in six areas of the axial zone of the Mid-Atlantic Ridge (MAR), 12°–31° N have been studied. The results of this study provided information on the composition of the parent melts for these glasses and made it possible to assess probable geochemical effects reflecting the interaction of magmatic melts with hydrothermal systems of the MAR axial zone or with altered oceanic crust (AOC). It is shown that basalts of the E-MORB family which includes most of samples are localized mainly in the “cold” segments of the MAR in the crustal section of which serpentinites predominate. On the other hand, samples with depleted signature (N-MORB) belong to segments of the MAR in which serpentinite outcrops are either absent or play a subordinate role. The E-MORB chilled glasses from “cold” segments of the MAR show signs of contamination of basaltic melts with components borrowed either from the host serpentinites or from aqueous-saline fluids circulating in hydrothermal systems located in serpentinites (“serpentinite hosted”). Judging by the data obtained on the nature of variations in the content of Cl, U, and Sr in the studied chilled glasses belonging to the N-MORB family, there are no signs of intracrustal contamination. It is assumed that relics of the ancient continental lithosphere preserved under axial zone of the MAR and involved in the process of partial melting of the shallow mantle took part in the formation of E-MORB parental melts in some segments of the MAR.

A reconstruction of metamorphic stages of Moren and Erzin metamorphic Complexes in the Khan-Khuhay block of Nothern Mongolia presented in the paper. Based on it a general geodynamic history of Sangilen terrain of Tuva-Mongolia Massif discussed. Reconstructed “clock-wise” P-T trend demonstrated two stage of metamorphism, the first of which is due to collision metamorphism with P-T parameters of 9 kbar, 740°C, the second one is due to regional magmatic episode with P-T parameters of 6-7 kbar, 860–880°C. Geochemical and petrological peculiarities of rocks in the Khan-Khuhay block demonstrates resemblance with metamorphic block of Western Sangilen in South-East Tuva. In the first time quartz monzodiorite intrusive bodies founded within Khan-Khuhay block. Their geochemical peculiarities are similar to Ordovician gabbro-monzodiorite intrusives of Western Sangilen. Quartz monzodiorite intrusives of Khan-Khuhay are likely a small apophysis of a deep-crust intermediate magma chamber and can present probable thermal source of metamorphic stage M2 in the Khan-Khuhay block. Numerical thermo-mechanical model of metamorphism in the Khan-Khuhay block explain heating in the thickening crust during collision due to higher radiogenic heat source of 1.52 μW/m³. Using computer modeling was show that the P-T parameters of second metamorphic stage can realize only by means of magmatic heat from monzodiorite intrusion. Reconstruction of P-T parameters using mineral thermobarometry, similarity of geochemical characteristics, as well as the results of thermomechanical modeling allow us to conclude that the Erzin and Moren complexes have undergone a joint tectono-metamorphic evolution.

An updated version of the COMAGMAT-5.3 program is presented, which enables simulations of the silicate-sulfide immiscibility in parallel to crystallization of Al-Cr spinel and other rock-forming minerals. Main changes include a completed recalibration of the previous Fe-Ni sulfide solubility model (Ariskin et al., 2013) and incorporation of equations describing spinel-melt equilibria in a wide range of magmatic systems (Nikolaev et al., 2018а, 2018b). This allowed us to specify more accurately the link between compositions of immiscible sulfides and magma crystallization temperatures, as well as to correct partitioning of alumina between the model spinel and crystallizing melt. The updated COMAGMAT-5.3 can be used for calculations of the crystallization of basaltic to komatiitic magmas, as well as the history of solidification of mafic to ultramafic cumulates, including relative proportions of Al-Cr spinel and immiscible sulfides. Application example includes solidification of sulfide-bearing primitive olivine cumulate from the endocontact of the Yoko-Dovyren intrusion in Northern Transbaikalia (Russia). It is established that maximum crystallization proportions of Al-Cr spinel as much as 3.5 wt % are observed at Ol-Spl cotectic, following an abrupt decrease to slightly negative values during crystallization of plagioclase-bearing assemblages. This results in the inflection point on the trend of evolution of the spinel compositions, which changes from descending the Cr/Al ratio in the field of olivine to its increase when plagioclase starts to crystallize. As compared to previous version COMAGMAT-5.2, the updated model predicts somewhat higher proportions of precipitated sulfides.