Microprobe Analysis of Titanium in Zircon: an Estimation of Secondary Fluorescence

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Abstract

Microprobe study of the effects of secondary fluorescence from high-titania glass (TiO2 ≈ 16 wt %) on apparent titanium content in Ti-free zircon was conducted. It was demonstrated that small crystals (<10 µm) are not suitable for analysis. In boundary parts of large zircon crystals (20–30 µm) the error in Ti estimation may reach 10–23%. However, in central parts of large crystals (> 30 µm) the microprobe analysis gives practically undistorted titanium contents.

About the authors

A. A. Borisov

Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry,
Russian Academy of Sciences

Author for correspondence.
Email: aborisov@igem.ru
Russia, Moscow

S. E. Borisovskiy

Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry,
Russian Academy of Sciences

Email: aborisov@igem.ru
Russia, Moscow

A. N. Koshlyakova

Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry,
Russian Academy of Sciences; Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences

Email: aborisov@igem.ru
Russia, Moscow; Russia, Moscow

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Copyright (c) 2023 А.А. Борисов, С.Е. Борисовский, А.Н. Кошлякова

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