Spectral Properties of Functional Distyryl Derivatives of BODIPY

A. A. Pakhomov; Пахомов А. А.; A. V. Efremova; Ефремова А. В.; M. A. Maksimova; Максимова М. А.; Yu. N. Kononevich; Кононевич Ю. Н.; D. S. Ionov; Ионов Д. С.; N. O. Dubinets; Дубинец Н. О.; V. I. Martynov; Мартынов В. И.; A. M. Muzafarov; Музафаров А. М.; M. V. Alfimov; Алфимов М. В.

doi:10.31857/S0023119323030105

Spectral Properties of Functional Distyryl Derivatives of BODIPY

Autores: Pakhomov A.¹^,2, Efremova A.², Maksimova M.³, Kononevich Y.², Ionov D.⁴, Dubinets N.⁴, Martynov V.¹, Muzafarov A.²^,5, Alfimov M.⁴^,6
Afiliações:
1. Shemyakin and Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences
2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
3. Faculty of Chemistry, Moscow State University
4. Photochemistry Center, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences
5. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
6. Moscow Institute of Physics and Technology (State University)
Edição: Volume 57, Nº 3 (2023)
Páginas: 177-185
Seção: ФОТОНИКА
URL: https://journals.rcsi.science/0023-1193/article/view/139972
DOI: https://doi.org/10.31857/S0023119323030105
EDN: https://elibrary.ru/KDPLDV
ID: 139972

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Resumo

The photophysical properties of functional distyryl derivatives of dipyrrometheneboron difluoride (BODIPY) in various solvents have been studied. It was shown that in all solvents, the studied compounds have similar absorption and fluorescence spectra, which are characteristic of the distyryl derivatives of BODIPY. Small bathochromic shifts of the spectra with increasing solvent polarity, as well as insignificant changes in the rate constants of radiative and nonradiative processes, provide evidence that the S1 states are of the (π,π*) type. These dyes can be used to visualize processes in living systems.

Palavras-chave

BODIPY, fluorescence, solvatochromism

Bibliografia

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