Open Access Open Access  Restricted Access Access granted  Restricted Access Subscription Access

No 1 (2025)

Cover Page

Full Issue

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Soil Fertility

Changes in the acid-base properties of sod-podzolic light loam soil during periodic liming

Pasynkov A.V., Pasynkova E.N., Ivanov A.A., Kupreeva A.V., Razumovskaya S.Y., Shikhametov E.M.

Abstract

In a field experiment in the link of the grain-grass crop rotation (barley with sowing of clover and phleum –perennial grasses of the 1st and 2nd year of use), changes in the acid-base properties of sod-podzolic light loamy soil during periodic liming were studied in order to establish optimal doses of lime with its long-term periodic use. A comparison of the average yields of barley grain and hay of perennial grasses over 3 years of testing in variants with single and periodic liming showed the advantage of periodic lime application in a dose of 1.0 Ha. In the variant with periodic lime application of 1.0 Ha, the acidity was significantly lower than in the control and in the variants with doses of 0.5 and 0.25 Ha, while the latter variants did not differ significantly in terms of acidity. Periodic liming led to a significant decrease in the content of Al3+, Fe and Mn. At the same time, there was a significant increase in S and V indicators and a decrease in Ha. No significant changes in the content of phosphorus, potassium and humus under the influence of periodic application of lime have been established. It was shown that the optimal dose of lime for its periodic use is 1.0 Ha.

Agrohimiâ. 2025;(1):3-10
pages 3-10 views

Potassium sorption by saline soils of Western Transbaikalia

Sosorova S.B., Merkusheva M.G., Lavrentieva I.N., Bologneva L.N.

Abstract

For the first time, potassium sorption in saline soils of Western Transbaikalia was studied under static conditions and a quantitative assessment of its parameters was given. It was found that the Langmuir and Freundlich equations satisfactorily describe the adsorption of potassium by the studied soils. It was shown that the maximum sorption capacity of soils (Amax) with respect to potassium varied within 5.1–137 mM K+/kg, which indicated a difference in sorption sites. A relatively high sorption of K+ by gley and typical salt marshes was revealed. The Amax value in the humus horizons varied by 2.6 times, in the underlying horizons – by 15.6 times and was minimal in the quasi-clay salt marsh. The adsorption equilibrium constant (CL) varied in a wide range from 0.32 to 26.8 l/mM with lower values in humus horizons, which indicated less strong binding of potassium in them. The values of the capacity coefficient of the Freundlich equation (KF) ranged from 3.1 to 91 l/kg=mM K+/kg in the humus horizon, from 3.2 to 69.5 in the mineral horizon. High values of the distribution coefficient (Kd) were typical for gley salt marsh and low values for quasi-gley (4.28–184 l/kg). A relatively high value of the maximum buffer capacity in relation to potassium (MBEc) was found in the gley and typical salt marshes, and a relatively minimum value was found in quasi-gley. According to the ability to sorb potassium, the saline soils of Western Transbaikalia formed the following decreasing series (weighted average in a layer of 0–30 cm): gley salt marsh > typical salt marsh > alluvial light humus saline > salt marsh > dark salt marsh > quasi-clay salt marsh. There was no clear correlation between the parameters of potassium adsorption and some indicators of soil properties. Only a weak dependence of the absorption of potassium ions on the reaction of the soil environment and the content of physical clay was observed.

Agrohimiâ. 2025;(1):11-25
pages 11-25 views

Effect of agrochemicals based on animal by-products, sewage sludge on the nitrogen regime of sod-podzolic soil, productivity and macronutrient composition of cereals

Kasatikov V.A., Shabardina N.P.

Abstract

The effect and aftereffect of agrochemicals obtained by mesophilic-thermophilic composting of organogenic by-products (manure of cattle, bird droppings and a mixture of urban wastewater sediment with sawdust) on the nitrogen regime of sod-podzolic sandy loam soil, the productivity of cereals in the crop rotation, their macronutrient composition were studied. It is concluded that these agrochemicals based on by-products of animal husbandry and sewage sludge significantly influenced the nitrogen regime of the soil, the productivity of the grain component of crop rotation and the macronutrient composition of crops.

Agrohimiâ. 2025;(1):26-30
pages 26-30 views

Fertilizers

Effectiveness of sulfur-containing fertilizers in the cultivation of peas in the conditions of chernozem soils of the Kursk Region

Minchenko J.N., Lazarev V.I.

Abstract

In an experiment on typical deep, heavy loamy chernozem conducted in 2018–2020 in the Kursk FASC, the effect of various doses of sulfur-containing fertilizer NPKS(10–20–20–6) on the yield and quality of pea grain of the Pharaoh variety was studied in the following variants: 1 – control without fertilization, 2 – NPKS(10–20–20–6) at a dose of N20P40K40S12 from autumn for basic tillage + N20 (ammonium nitrate) in spring for pre-sowing cultivation, 3 – NPKS(10–20–20–6) at a dose of N30P60K60S18 from autumn for basic tillage + N30 (ammonium nitrate) in spring for pre-sowing cultivation, 4 – NPK(16–16–16) at a dose of N40P40K40 (250 kg/ha) from autumn for basic tillage, 5 – NPK(16–16–16) at a dose of N60P60K60 (375 kg/ha) from autumn for basic tillage. It was shown that in conditions of chernozem soils with a low level of sulfur availability (4.5 mg S/kg), its introduction into the soil as part of the complex mineral fertilizer NPKS(10–20–20–6) increased the yield of peas by 1.9–1.6 c/ha, the protein content in the grain – by 0.4–0.5% compared to the application of a complex mineral fertilizer without sulfur (NPK16–16–16). The use of sulfur-containing fertilizer NPKS(10–20–20–6) in pea crops was economically profitable: the net income from its application was 3 901–6 612 rubles/ha, the profitability level was 68.0–85.4%, with the values of these indicators in the control variant equal to 15 312 rubles/ha and 65.9%, respectively. Increasing the dose of sulfur-containing fertilizer NPKS(10–20–20–6) to N60P60K60S18 was not economically feasible.

Agrohimiâ. 2025;(1):31-38
pages 31-38 views

Use of nitrogen leaf fertilizing to increase the yield of tomatoes in the Astrakhan Region

Tyutyuma N.V., Bondarenko A.N.

Abstract

The possibility of improving the zonal technology of cultivating tomatoes in the open ground using leaf fertilizing with KCl and KNO3 aimed at increasing yields during irrigation in the conditions of the north of the Astrakhan region was investigated. Field experiments were conducted on an experimental irrigated land use site of the Caspian Agrarian Federal Scientific Center of the Russian Academy of Sciences in the period from 2021 to 2023. The scientific novelty of the study consisted in the theoretical and practical justification of the use of leaf fertilizers with KCl and KNO3 in the cultivation of vegetable crops aimed at the formation of highly productive marketable products. A comparative analysis of different doses of fertilizers was carried out with the selection of the most promising option. Three-year studies have found that the use of KCl of 0.5% fertilizer on the 30–40th day after planting seedlings (flowering phase), on 50th and 60th day after planting gave a significant increase in yield relative to the control. According to the results of the analysis, on average for 5 croppings, the background + 3 KCl treatment option (concentration 0.5%) was identified as the one resulting in the highest yield – 131 t/ha. This option differed significantly from both the control and other studied options. The increase in yield relative to the control was 4.08 t/ha or 3.2%.

Agrohimiâ. 2025;(1):39-46
pages 39-46 views

Plant growth regulators

Participation of jasmonic acid in the long-distance signalling from roots to shoots of peas plants under saliny

Akhiyarova G.R., Vafina G.K., Korobova A.V., Ivanov I.I., Giniyatullin A.R., Gaffarova E.R., Garipova M.I., Kudoyarova G.R.

Abstract

Jasmonic acid (JA) and its derivatives are involved in the adaptation of plants to biotic and abiotic stresses, including salinization. However, there is insufficient information about the role of JA in the transmission of signals from organ to organ under the local action of abiotic factors. The signaling role of JA in connection with the reaction of shoots to salinization of the root environment of pea plants has been studied. The results of the effect of salinization on changes in the content of JA in the growing and conducting zones of roots and xylem sap, as well as the localization of JA and abscisic acid (AA) in the leaves of stressed plants due to changes in their transpiration level are presented. The content and localization of JA in leaves and roots of plants were evaluated by immunohistochemical method using specific antibodies. The purpose of this study is to check whether salinity-induced changes in the concentration of JA in roots and xylem sap can explain the accumulation of these hormones in leaves and related transpiration changes.

Agrohimiâ. 2025;(1):47-54
pages 47-54 views

Agroecology

Stocks, chemical composition of grassland litter and felts of Leymus communities (Leymus chinensis (Trin.) Tzvel.) in the south of Eastern Transbaikalia and assessment of their resistance to decomposition

Merkusheva M.G., Boloneva L.N., Lavrentieva I.N., Badmaeva N.K.

Abstract

The reserves and chemical composition of grassland litter and felts in monodominant Leymus chinensis communities of the southern part of Eastern Transbaikalia, growing in different soil and ecological conditions of a distinctly continental climate and performing protective functions in winter for the thermal and water regimes of the upper soil horizons, the preservation of plant renewal buds, are studied. It was revealed that the stocks of grassland litter and felts varied significantly: 2.9–102.9 and 54–107 g/m2, respectively. The amount of grassland litter mainly depended on the species composition of communities and the degree of pasture load. A correlation was established between the accumulation of grassland litter and felts from the dominant production and the total green phytomass of leymus communities, but the relationship between the content of grassland litter and felts in leymus communities was weak (r = 0.44). To restore the optimal accumulation of rags, according to the values of the litter fall coefficient (LFC) and the destruction coefficient (Kd), will take a relatively long time. A high negative correlation between these indicators was revealed (r = – 0.89... –0.91). Concentrations of macronutrients in grassland litter and felts from different communities were determined by species composition and availability of nutrients and moisture. According to the values of the C : N, C : P, C : N : S : P, Ca : K and Si : Ca ratios in the aboveground phytomass of communities, it was shown for the first time that the grassland litter and felts of leymus communities in the southern part of Eastern Transbaikalia are resistant to decomposition and mineralization. However, the degree of stability can be adjusted with changes in species composition, climatic (drought, heavy rainfall) and anthropogenic (spring snowfall and steppe fires) conditions.

Agrohimiâ. 2025;(1):55-65
pages 55-65 views

Ecotoxicology

Diagnostic value of some indicators of soil nitrogen regime for assessing the ecological state of oil-pollutant soils

Gerasimov А.О., Polyak Y.М., Bakina L.G.

Abstract

The results of studies of the nitrogen regime of oil-contaminated soils in recent years are considered. Insufficient knowledge of this issue for man-made soils is emphasized, despite the fact that soil pollution with oil and petroleum products can cause significant changes in the nitrogen cycle and lead to irreversible violations of the ecological functions of soils. The generalization of the research results made it possible to identify the most informative indicators for assessing the processes of the nitrogen regime and the ecological state of oil-contaminated soils. Under conditions of oil pollution, the ratio of carbon and nitrogen contents in the soil increases, the nitrifying activity of soils decreases, and the proportion of ammonium forms of nitrogen increases relatively. It is shown that violations of the processes of the nitrogen cycle, the content and the ratio of the contents of different forms of nitrogen characterizing certain stages of its transformation in the soil can be restored to varying degrees during reclamation, depending on the properties of the soil. At the moment, the most promising areas of research into the processes of the nitrogen cycle in oil-contaminated soils are: the study of the vital activity of soil microorganisms carrying out various stages of the nitrogen cycle processes, the relationship of the structure and diversity of the microbiota with the rate of biodegradation of oil and transformation of nitrogen compounds in contaminated soils. The study of the nitrogen cycle processes is important for assessing the effects of soil pollution with petroleum products and choosing the most effective strategies for their restoration.

Agrohimiâ. 2025;(1):66-74
pages 66-74 views

Content of heavy metals in agrochernozem of the Southern Cis-Urals after introduction of sewage sludge as a fertilizer

Melentyeva O.A., Gabbasova I.M., Garipov T.T., Khabirov I.K.

Abstract

The study was conducted in the southern forest-steppe of the Republic of Bashkortostan on heavy loamy agrochernozem with a high content of humus, close to a neutral pH, high capacity of cation exchange with a predominance of calcium. Sewage sludge (SS) from Ufa municipal wastewater treatment plants was introduced at a dose of 30 t/ha in the top layer of 0–20 cm of soil. Samples were taken from depths of 0–5, 5–20 and 20–40 cm six months after application. The introduction of SS led to an increase in the content of humus, mineral nitrogen (up to 2.5 times), mobile phosphorus (up to 30%) and exchangeable potassium (up to 12%), as well as the neutralization of the soil solution. At the same time, the content of mobile forms of heavy metals (HM) Mn, Cu, Zn, Co, Pb and Cd did not exceed 16.6% of the model predictive control (MPC), the content of gross forms of As, Zn, Pb, Hg, Cd, Cr, Co, Cu and Mn did not exceed 51% of the MPC, the total chemical index of the HM content was “acceptable” (2.6–10.2). Only the concentration of Ni, which was 0.75 MPC in the background soil, increased to 0.8 MPC. Consequently, the nickel content was a limiting factor in the introduction of SS, and it was a key element for monitoring the content of HM in soils.

Agrohimiâ. 2025;(1):75-80
pages 75-80 views

Effect of fertilizers and meliorants on the mobility of Cd, Pb, Cu and Zn in layers of leached heavy loam chernozem

Pugaev S.V., Prokina L.N.

Abstract

The degree of mobility (DM) of Cd, Pb, Cu and Zn in arable (0–20 cm) and sub-arable (21–40 cm) soil layers was studied when applying phosphorus-potassium and nitrogen fertilizers on the background of liming and without it. It was revealed that the values of the DM of heavy metals (HM) were mainly lower during liming. In Cu, it varied less significantly compared to other metals. Fertilizers on the background of liming significantly lowered the Cd loss compared to the control, and without it – increased it in both layers. The vector of changes in the DM of the metal in the layers during liming depended on the doses of nitrogen in the NPK complex. Phosphorus-potash fertilizers reduced the DM of metals, and liming enhanced their effect. The values of DM decreased to a minimum with the use of PK- and NK-fertilizers with a low dose of nitrogen in liming conditions and without it, and increased with a maximum dose of nitrogen. Liming increased the differences in the joint venture between the layers in the nitrogen-free versions, and significantly reduced them when applied. Liming did not change the location of the metals in terms of their DM under experimental conditions: Cd > Pb > Zn > Cu.

Agrohimiâ. 2025;(1):81-88
pages 81-88 views

Reviews

Modern trends in the use of pesticides and methods for their determination in agricultural products

Bragin A.A., Bazyk A.D., Pavlova N.A.

Abstract

Many active substances of pesticides are dangerous toxicants that can disrupt the stability of natural and agricultural ecosystems and cause irreversible harm to human health when ingested. In addition, from several units to several dozens of new active substances of pesticides and products based on them are developed annually. This determines the critical need to control their use and content in environmental objects, especially in agricultural products. The development of modern chemical analytical methods helps to increase the effectiveness of such control. Improving the methods of extracting pesticides from extremely complex matrices of soils and agricultural products can significantly speed up and reduce the cost of conducting a single analysis, and improving analytical equipment allows to determine the picogram contents of target pesticides or conduct monitoring studies of samples to identify pollutants.

Agrohimiâ. 2025;(1):89-104
pages 89-104 views

Согласие на обработку персональных данных с помощью сервиса «Яндекс.Метрика»

1. Я (далее – «Пользователь» или «Субъект персональных данных»), осуществляя использование сайта https://journals.rcsi.science/ (далее – «Сайт»), подтверждая свою полную дееспособность даю согласие на обработку персональных данных с использованием средств автоматизации Оператору - федеральному государственному бюджетному учреждению «Российский центр научной информации» (РЦНИ), далее – «Оператор», расположенному по адресу: 119991, г. Москва, Ленинский просп., д.32А, со следующими условиями.

2. Категории обрабатываемых данных: файлы «cookies» (куки-файлы). Файлы «cookie» – это небольшой текстовый файл, который веб-сервер может хранить в браузере Пользователя. Данные файлы веб-сервер загружает на устройство Пользователя при посещении им Сайта. При каждом следующем посещении Пользователем Сайта «cookie» файлы отправляются на Сайт Оператора. Данные файлы позволяют Сайту распознавать устройство Пользователя. Содержимое такого файла может как относиться, так и не относиться к персональным данным, в зависимости от того, содержит ли такой файл персональные данные или содержит обезличенные технические данные.

3. Цель обработки персональных данных: анализ пользовательской активности с помощью сервиса «Яндекс.Метрика».

4. Категории субъектов персональных данных: все Пользователи Сайта, которые дали согласие на обработку файлов «cookie».

5. Способы обработки: сбор, запись, систематизация, накопление, хранение, уточнение (обновление, изменение), извлечение, использование, передача (доступ, предоставление), блокирование, удаление, уничтожение персональных данных.

6. Срок обработки и хранения: до получения от Субъекта персональных данных требования о прекращении обработки/отзыва согласия.

7. Способ отзыва: заявление об отзыве в письменном виде путём его направления на адрес электронной почты Оператора: info@rcsi.science или путем письменного обращения по юридическому адресу: 119991, г. Москва, Ленинский просп., д.32А

8. Субъект персональных данных вправе запретить своему оборудованию прием этих данных или ограничить прием этих данных. При отказе от получения таких данных или при ограничении приема данных некоторые функции Сайта могут работать некорректно. Субъект персональных данных обязуется сам настроить свое оборудование таким способом, чтобы оно обеспечивало адекватный его желаниям режим работы и уровень защиты данных файлов «cookie», Оператор не предоставляет технологических и правовых консультаций на темы подобного характера.

9. Порядок уничтожения персональных данных при достижении цели их обработки или при наступлении иных законных оснований определяется Оператором в соответствии с законодательством Российской Федерации.

10. Я согласен/согласна квалифицировать в качестве своей простой электронной подписи под настоящим Согласием и под Политикой обработки персональных данных выполнение мною следующего действия на сайте: https://journals.rcsi.science/ нажатие мною на интерфейсе с текстом: «Сайт использует сервис «Яндекс.Метрика» (который использует файлы «cookie») на элемент с текстом «Принять и продолжить».