Vol 57, No 1 (2016)
- Year: 2016
- Articles: 23
- URL: https://journals.rcsi.science/1083-4877/issue/view/15484
Refractories in Heating Units
Improving the Designs of Elements of Refractory Materials for the Tundish of Continuous Section Casters
Abstract
This article examines the designs of sets of equipment installed in the discharge chambers of the tundishes on continuous section casters. Further refinement and practical introduction of the designs will effectively extinguish the eddies that form above the discharge nozzles and improve the quality of the castings by forming a well-organized stream of molten metal.
Article
Study of Local (Pitting) Wear of the Periclase-Carbon Lining of a Ladle
Abstract
Astudy is made of local (pitting) wear of the working layer of a periclase-carbon lining in a steel-pouring ladle used in a ladle-furnace unit without vacuum degassing of the steel that is being treated. The main causes of this type of wear are evaluated.
Technologies for Controlling Flows of Steel and the Development of Refractory Structures for the Tundish of a Four-Strand Continuous Caster
Abstract
This article examines the configuration of elements of the chambers of a tundish on a four-strand continuous caster and aspects of organizing the movement of the flows of steel within the chambers. It is shown that new configurations and structural elements developed for the system that distributes the flows have a significant effect on their parameters and the removal of nonmetallic inclusions. The equipment upgrade ensures efficient formation of the flows and creates the conditions necessary to improve the quality of the cast steel.
Thermophysical Properties of Carbon-Carbon Materials Based on Graphite Foam
Abstract
Laser flashing and thermal analysis are used to determine thermal conductivity and linear thermal expansion coefficient of low density carbon-carbon materials based on two types of graphite foam differing in degree of graphite matrix defectiveness, and pyrocarbon. It is shown that density after compaction and not the ratio of carbon components has the main effect on thermal conductivity. Carbon-carbon material based on electrochemical graphite foam has low values of thermal conductivity λ = 0.5 – 2.0 W/(m·K) over a wide temperature range (30 – 900°C), whereas for specimens based on traditional graphite foam low values of λ are only typical at high temperature.
Research in the Area of Preparing Materials Based on Fuzed Quartz HCBS. Part 8. Effect of Alkali Additions on Ceramic Sintering and Cristobalitization in a Nonisothermal Heating Regime1
Abstract
Results are provided for a study of the effect of alkali additions based on dispersed silicate lump (sodium metasilicate) on quartz ceramic sintering and cristobalitization in a nonisothermal heating regime in a high-temperature dilatometer. Depending on additive content the difference in initial sintering temperature reaches 300°C, and for the initial stage of cristobalitization it reaches 400°C.
Synthesis and Conversion on Heating of Nickel-Containing Antioxidant Organic Precursor for Periclase-Carbon Refractories
Abstract
Results are given for a study of physicochemical processes occurring on heating synthesized antioxidant precursor, i.e., nickel oxalate salt. It is shown that after heating at 300°C NiO is formed that is an antioxidant. Salt before and after heat treatment at 300 – 500°C may be used as an antioxidant
Solar Technology for Obtaining Superconducting Ceramic Bi1.7Pb0.3Sr2Ca(n–1)CunOy (n = 3 – 5) and Studying its Properties
Abstract
A technology has been developed for synthesizing a superconducting ceramic from glassy-crystalline precursors having the nominal compositions (Bi1.7Pb0.3Sr2Ca(n–1)CunOy (n = 3 – 5). The ceramic is synthesized in a melt under the influence of solar radiation. The dependence of the formation of superconducting phases on the temperature-time conditions is studied, and the degree of texturing based on the Lotgering factor is evaluated in relation to the temperature of the ceramic’s heat treatment. The temperature at which the ceramic transitions to the superconducting state is determined (Tc = 107 – 138 K) along with its post-transition stability (>7 years).
Mechanochemically Activated Phosphate-Containing Refractory Composite Materials1
Abstract
Development of new highly efficient composite materials is an important area for effective activity of refractory enterprises. It is established that use of binder suspensions as both a mix component, and as an independent material, makes it possible to expand the field of developed material application. The efficiency of using corundum coatings increases heating unit service life.
Ceramic Material for Making Heat-Resistant Products
Abstract
It is shown that it is possible to obtain a highly thermally stable corundum material with minimal preparation of the raw materials that are used. The corundum material can be employed in the production of parts for the insulators of molybdenum heaters in the furnaces of gasostats used for gasostatting cast vanes made of superalloys.
Corrosion Resistance of Chromium-Containing Refractories in Molten Alkali-Free Borosilicate Glass E
Abstract
Information is provided for chromium-containing refractory used in founding alkali-free borosilicate glass E. It is shown that melted and cast chromespinelid refractory KhPL-85 developed, containing 80% Cr2O3 with respect to corrosion resistance in molten glass E, is at the same level as industrial chromium oxide refractories.
Oxide Ceramic Surface Layer Modification Using Continuous Laser Radiation
Abstract
Features of laser modification of a ceramic surface layer based on aluminum oxide under action of continuous laser radiation are studied. The effect of a continuous laser action regime on track formation geometric parameters, and oxide ceramic surface layer morphology and defectiveness is determined. The main types of recurrent microstructures formed within a ceramic modified surface layer are identified and studied.
Effect of Firing Temperature and Gas Atmosphere on Acid-Resistant Material Pore Structure Formation
Abstract
A dependence is established for acid-resistant material pore structure on firing temperature and gas parameters. It is expedient to fire acid-resistant materials up to 1100°C in an oxidizing atmosphere, and at 1100 – 1200°C in a reducing atmosphere. With this regime firing provides an improvement for acid-resistant material pore structure.
Study of the Effect of pH Regulators and Polyelectrolytes on Lithium-Aluminum Silicate Glass Aqueous Suspension Parameters and Casting Properties
Abstract
Wet milling is used to prepare lithium-aluminum silicate glass suspensions. The possibility is studied of using electrostatic and electrosteric stabilization methods for controlling aqueous suspension parameters with the aim of reducing the duration of green workpiece setting with required density and porosity. Additives used are orthophosphoric and hydrochloric acids, aqueous ammonia solution, and also polyacrylic acid (PAA), and PAA sodium and ammonium salts.
Research in the Field of Preparing Molded and Unmolded Refractories Based on High-Alumina HCBS. Part 4. Effect of Refractory Clay Additions on Properties of Compound Composition HCBS, Castings, and Materials Based on Them
Abstract
Examples are provided of the efficiency of adding refractory clays in HCBS technology and ceramic concretes. Properties of castings prepared by slip casting based on HCBS of composite composition in bauxite – very fine quartz glass (VFQG), and additions of refractory clay (1 – 10%) are studied. The effect of continuous nonisothermal heating up to 1500°C on specimen linear dimensions is studied by means of a high-temperature dilatometer. Data obtained are compared with specimen apparent porosity after isothermal firing with soaking for 1 h in the range 800 – 1500°C. Maximum linear shrinkage with nonisothermal heating and minimum value of apparent porosity after isothermal firing correspond to the range 1200 – 1500°C. Maximum indices are noted at 1500°C for both specimen growth and also porosity due to occurrence of secondary mullitization.
Varying the Granulometric Composition of an Electrofused-Corundum-Based Ceramic with a Porcelain Binder to Control its Open Porosity and Strength
Abstract
A study is made of a strong porous ceramic based on granular mixes of a filler—electrofused corundum with particle sizes of 2 – 3 and 0.5 mm (95 wt.% of the mix) — and a porcelain binder (5 wt.%). Several mixes were prepared with different values for the 2 – 3 mm/0.5 mm ratio of filler-particle sizes: 0/95, 35/60, 40/55, 45/50, 50/45, and 95/0. The specimens were pressed at pressures of 25, 50 and 100 MPa and fired at temperatures of 1350 and 1450°C. The sintered specimens ranged from 19 to 143 MPa in ultimate flexural strength and 17 to 26% in open porosity. The results are attributed to the formation of a framework in the semifinished product along with regions outside the framework. The new porous permeable ceramic is promising for use in the form of filters and supports for ceramic membranes.
Alumo-Yttrium Garnet Crucibles Made by Slip Casting for Work with High-Purity Powders
Abstract
The method of slip casting is used to make dense ceramic crucibles of cerium-doped alumo-yttrium garnet. Use of the crucibles to heat-treat this material does not lead to its contamination at temperatures up to 1600°C. A laboratory technology for making the crucibles is described.
Effect of Solid Reagent Dispersion in Heterogeneous Chemical Reactions
Abstract
A new type of heterogeneous process is considered, i.e., a solid – liquid type self-accelerating heterogeneous reaction. For these processes there is a typical development stage of a progressive increase in reaction surface, caused by solid phase dispersion. Steel corrosion in hydrochloric acid, reaction of boron nitride with molten alkali, molten silicon phosphate with carbon reducing agent, hematite with molten silicate, and molten iron with hematite ceramic, are studied. The effect of solid phase dispersion as an independent stage of chemical reaction is confirmed by experiment. Possible process mechanisms are suggested.
Corundum and Zirconia Composites Based on Artificial Ceramic Binders
Abstract
Research is carried out on different types of artificial ceramic binders based on single-crystal and polycrystalline zirconia and corundum composition raw material. Features are established for composite compaction in relation to molding conditions and raw material type. The possibility is demonstrated of using these binders for preparing high density ceramic composites with improved operating properties.
Analysis of Oxide-Carbide Ceramic Surface Layer Stress-Strained State with Jet-Abrasive Treatment
Abstract
Results are given for modeling the stress-strained state of an oxide-carbide surface layer with jet-abrasive treatment using a developed research method of system combination. Stress and strain are analyzed in Al2O3–MgO system ceramic under action of different loads. The possibility is determined of using the dependences revealed for constructing a model of ceramic surface formation during jet-abrasive treatment.
Production and Equipment
Capturing Nanoparticles in Alumina Production
Abstract
The movement of charged dust particles of different sizes in an electrostatic precipitator is studied. It is found that such particles acquire different velocities before they are deposited in the precipitator. They differ significantly from one another in the curvature of their trajectories, which makes it easier to precipitate nanoparticles from the general dust-air flow. A unit is proposed for capturing the nanosized fraction of dust particles in the upward pneumatic transport of bulk materials during alumina production.
Heat Engineering
Production of Foamed Vermiculite from Conglomerates in Modular-Pouring Electric Furnaces
Abstract
A technology for firing vermiculite conglomerates with a high content of inert material is examined. The firing operation is completed in an additional “zero” module by the internal heat accumulated in the conglomerate itself. Heat is transferred by radiation from particles of the inert material to the vermiculite granules inside the conglomerate. At the same time, heat is being transferred by conduction from the outer layers of the granules to their inner layers. Such a method of using recuperated heat makes it possible to mitigate the temperature regime of the electric modules, reduce the consumption of electric power, and decrease the energy content of the process.
Scientific Research and Development
Study of the Structure and Properties of Graphites for Refractory Production. Part 2. Properties of Periclaseand Corundum-Graphite Refractories with Introduction into Their Composition of Graphite from Different Producers1
Abstract
are provided for a study of the effect of different graphites GÉ-1 and GCh (Russian Federation), Falke 94100 and Falke 9280 (Brazil), +592 (PRC), +595 (Madagascar), and FLS 897 (Norway) on physicochemical properties of periclase- and corundum-graphite refractories. It is shown that the type of graphite affects charge properties even in the preparation stage, and object physicochemical properties.
Ecology
Modeling of Air and Dust Flows in the Range of Action of a Round Suction Funnel Above an Impermeable Plane. Part 2. Characteristics of Separation Region and Efficiency of Capture of Dust Particles1
Abstract
Current near a round local ventilation suction port in the form of a funnel situated above an impermeable plane is considered. Limiting trajectories of dust particles are constructed in the velocity field found from a new computer program and the capture coefficient as a function of the slope and length of the funnel and distance from the plane is determined. The geometric dimensions of the separation region at the inlet to the funnel as functions of the distance from the plane and the length of the funnel are determined.