Kinetics of the Dissociation of Cu2+ and Co2+ Complexes of Nitro Derivatives of 5,15-Diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin in Proton-Donor Media
- 作者: Kuvshinova E.1, Vershinina I.2, Islyaikin M.1, Syrbu S.1, Golubchikov O.1
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隶属关系:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- 期: 卷 89, 编号 3 (2019)
- 页面: 570-573
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222825
- DOI: https://doi.org/10.1134/S107036321903037X
- ID: 222825
如何引用文章
详细
Copper and cobalt complexes of nitro derivatives of planar and nonplanar derivatives of 5,15-diphenyl- 3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin are synthesized and their stability in proton-donor media is investigated. It is established that the kinetic parameters of the dissociation reactions of copper and cobalt complexes of the studied porphyrins depends on the degree of deformation of the porphyrin macroring and the acceptor properties of NO2 groups.
作者简介
E. Kuvshinova
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: kuvshinovae@isuct.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
I. Vershinina
Krestov Institute of Solution Chemistry
Email: kuvshinovae@isuct.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040
M. Islyaikin
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
O. Golubchikov
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300