Email this article Kinetics of the Dissociation of Cu2+ and Co2+ Complexes of Nitro Derivatives of 5,15-Diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin in Proton-Donor Media
- Authors: Kuvshinova E.M.1, Vershinina I.A.2, Islyaikin M.K.1, Syrbu S.A.1, Golubchikov O.A.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Issue: Vol 89, No 3 (2019)
- Pages: 570-573
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222825
- DOI: https://doi.org/10.1134/S107036321903037X
- ID: 222825
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Abstract
Copper and cobalt complexes of nitro derivatives of planar and nonplanar derivatives of 5,15-diphenyl- 3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin are synthesized and their stability in proton-donor media is investigated. It is established that the kinetic parameters of the dissociation reactions of copper and cobalt complexes of the studied porphyrins depends on the degree of deformation of the porphyrin macroring and the acceptor properties of NO2 groups.
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About the authors
E. M. Kuvshinova
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: kuvshinovae@isuct.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
I. A. Vershinina
Krestov Institute of Solution Chemistry
Email: kuvshinovae@isuct.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
M. K. Islyaikin
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
S. A. Syrbu
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
O. A. Golubchikov
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
