Отправить статью по E-mail Kinetics of the Dissociation of Cu2+ and Co2+ Complexes of Nitro Derivatives of 5,15-Diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin in Proton-Donor Media
- Авторы: Kuvshinova E.1, Vershinina I.2, Islyaikin M.1, Syrbu S.1, Golubchikov O.1
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Учреждения:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Выпуск: Том 89, № 3 (2019)
- Страницы: 570-573
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222825
- DOI: https://doi.org/10.1134/S107036321903037X
- ID: 222825
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Аннотация
Copper and cobalt complexes of nitro derivatives of planar and nonplanar derivatives of 5,15-diphenyl- 3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin are synthesized and their stability in proton-donor media is investigated. It is established that the kinetic parameters of the dissociation reactions of copper and cobalt complexes of the studied porphyrins depends on the degree of deformation of the porphyrin macroring and the acceptor properties of NO2 groups.
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E. Kuvshinova
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: kuvshinovae@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300
I. Vershinina
Krestov Institute of Solution Chemistry
Email: kuvshinovae@isuct.ru
Россия, ul. Akademicheskaya 1, Ivanovo, 153040
M. Islyaikin
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300
O. Golubchikov
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300
