Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes
- 作者: Loseva O.1, Rodina T.2, Antzutkin O.3,4, Ivanov A.1
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隶属关系:
- Institute of Geology and Nature Management, Far-East Branch
- Amur State University
- Luleå University of Technology
- University of Warwick
- 期: 卷 88, 编号 12 (2018)
- 页面: 2540-2549
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222589
- DOI: https://doi.org/10.1134/S1070363218120149
- ID: 222589
如何引用文章
详细
The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.
作者简介
O. Loseva
Institute of Geology and Nature Management, Far-East Branch
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, per. Relochnyi 1, Blagoveshchensk, 675000
T. Rodina
Amur State University
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, Blagoveshchensk
O. Antzutkin
Luleå University of Technology; University of Warwick
Email: alexander.v.ivanov@chemist.com
瑞典, Luleå; Coventry
A. Ivanov
Institute of Geology and Nature Management, Far-East Branch
编辑信件的主要联系方式.
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, per. Relochnyi 1, Blagoveshchensk, 675000