Email this article Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes
- Authors: Loseva O.V.1, Rodina T.A.2, Antzutkin O.N.3,4, Ivanov A.V.1
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Affiliations:
- Institute of Geology and Nature Management, Far-East Branch
- Amur State University
- Luleå University of Technology
- University of Warwick
- Issue: Vol 88, No 12 (2018)
- Pages: 2540-2549
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222589
- DOI: https://doi.org/10.1134/S1070363218120149
- ID: 222589
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Abstract
The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.
About the authors
O. V. Loseva
Institute of Geology and Nature Management, Far-East Branch
Email: alexander.v.ivanov@chemist.com
Russian Federation, per. Relochnyi 1, Blagoveshchensk, 675000
T. A. Rodina
Amur State University
Email: alexander.v.ivanov@chemist.com
Russian Federation, Blagoveshchensk
O. N. Antzutkin
Luleå University of Technology; University of Warwick
Email: alexander.v.ivanov@chemist.com
Sweden, Luleå; Coventry
A. V. Ivanov
Institute of Geology and Nature Management, Far-East Branch
Author for correspondence.
Email: alexander.v.ivanov@chemist.com
Russian Federation, per. Relochnyi 1, Blagoveshchensk, 675000
