Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes
- Авторлар: Loseva O.1, Rodina T.2, Antzutkin O.3,4, Ivanov A.1
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Мекемелер:
- Institute of Geology and Nature Management, Far-East Branch
- Amur State University
- Luleå University of Technology
- University of Warwick
- Шығарылым: Том 88, № 12 (2018)
- Беттер: 2540-2549
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222589
- DOI: https://doi.org/10.1134/S1070363218120149
- ID: 222589
Дәйексөз келтіру
Аннотация
The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.
Авторлар туралы
O. Loseva
Institute of Geology and Nature Management, Far-East Branch
Email: alexander.v.ivanov@chemist.com
Ресей, per. Relochnyi 1, Blagoveshchensk, 675000
T. Rodina
Amur State University
Email: alexander.v.ivanov@chemist.com
Ресей, Blagoveshchensk
O. Antzutkin
Luleå University of Technology; University of Warwick
Email: alexander.v.ivanov@chemist.com
Швеция, Luleå; Coventry
A. Ivanov
Institute of Geology and Nature Management, Far-East Branch
Хат алмасуға жауапты Автор.
Email: alexander.v.ivanov@chemist.com
Ресей, per. Relochnyi 1, Blagoveshchensk, 675000