Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide
- 作者: Popov R.1, Novikov A.1, Mikherdov A.1
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隶属关系:
- St. Petersburg State University
- 期: 卷 88, 编号 11 (2018)
- 页面: 2347-2353
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222538
- DOI: https://doi.org/10.1134/S1070363218110166
- ID: 222538
如何引用文章
详细
Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.
作者简介
R. Popov
St. Petersburg State University
Email: asm93@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Novikov
St. Petersburg State University
Email: asm93@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Mikherdov
St. Petersburg State University
编辑信件的主要联系方式.
Email: asm93@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034