Email this article Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide
- Authors: Popov R.A.1, Novikov A.S.1, Mikherdov A.S.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 88, No 11 (2018)
- Pages: 2347-2353
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222538
- DOI: https://doi.org/10.1134/S1070363218110166
- ID: 222538
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Abstract
Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.
About the authors
R. A. Popov
St. Petersburg State University
Email: asm93@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. S. Novikov
St. Petersburg State University
Email: asm93@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. S. Mikherdov
St. Petersburg State University
Author for correspondence.
Email: asm93@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
