Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles
- 作者: Mikherdov A.1, Orekhova Y.1, Boyarskii V.1
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隶属关系:
- St. Petersburg State University
- 期: 卷 88, 编号 10 (2018)
- 页面: 2119-2124
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222478
- DOI: https://doi.org/10.1134/S1070363218100158
- ID: 222478
如何引用文章
详细
The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl2(CNXyl)2], Xyl = 2,6-Me2C6H3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.
作者简介
A. Mikherdov
St. Petersburg State University
Email: v.boiarskii@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
Yu. Orekhova
St. Petersburg State University
Email: v.boiarskii@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
V. Boyarskii
St. Petersburg State University
编辑信件的主要联系方式.
Email: v.boiarskii@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034